The Manchester City winger was a surprise omission from Joachim Low's 23-man party for Russian Federation when the head coach cut four names from his preliminary group on Monday, Bayer Leverkusen's Julian Brandt getting the nod ahead of him.
Neuer is to join the starting lineup in Russian Federation despite having been out for eight months due to a foot injury, while Sane was passed over after having a stellar season with English Premier League (EPL) champions Manchester City, reported Efe.
Sane is yet to score for Germany in his 12 caps with the senior team, but had an impressive second season at Manchester City, where he scored 10 league goals and had 15 assists.
'There are better days in the life of a national team coach when you have to send four fantastic players, who deserve to be at the World Cup, home.
"It was a very tight decision".
"It was nearly like a 100-metre race at the Olympics, with a photo finish".
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Neuer, who played in Saturday's friendly against Austria following his eight-month absence, expressed his gratitude for all the support he has received while sidelined. I stayed positive through the injury and had I not been positive I would not have been included.
"During all that time, I tried to have a positive attitude, otherwise I wouldn't be here and I wouldn't have been called up", he said.
Goalkeepers: Manuel Neuer (C), Kevin Trapp and Marc-Andre ter Stegen.
"The decisions I and my coaches had to make were not easy".
Germany face Saudi Arabia in their final World Cup warm-up match on Friday before taking on Mexico, Sweden and South Korea in Group F.
Defenders: Jonas Hector, Antonio Rudiger, Joshua Kimmich, Mats Hummels, Jerome Boateng, Matthias Ginter, Marvin Plattenhardt and Niklas Sule. Petersen made his debut against Austria but Loew is keeping faith in forwards Timo Werner and Mario Gomez.